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cellspacing="0" cellpadding="0" align="left"> <tr> <td height="8"></td> </tr> <tr><td align="center" height="100" valign="top"> <table width="99%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr><td class=red_2 align=left><script src='/homes/Blog_tuijian.asp?Id=75578'></script></td></tr> <tr> <td align="left"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr> <td class="style_14_666666"> <div class="f401" id="f401"><p class="MsoNormal" style="text-indent:24.0pt;"> ç”׃ºŽé«˜å¼¹æ€§ï¼Œä½Žæ¨¡é‡çš„特点åQŒæ©¡èƒ¶çš„摩擦¼‚¨æŸæ€§èƒ½å—自íw«ç‰©ç†åŠ›å­¦æ€§èƒ½çš„媄响较大。橡胶的¼‹¬åº¦è¾ƒå°åQŒä¸Žåˆšæ€§ç‰©ä½“接触时åQŒçœŸå®žæŽ¥è§¦é¢¿U¯è¾ƒå¤§ï¼Œè€ŒçœŸå®žæŽ¥è§¦é¢¿U¯çš„大小是决定摩擦的重要因素åQŒå› æ­¤ï¼ŒŠ™¡èƒ¶çš„硬度对其摩擦性能的媄响较大ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> Š™¡èƒ¶çš„粘å¼ÒŽ€§å‚æ•?span>tan</span>δå¯ÒŽ‘©æ“¦åŠ›æœ‰ç›´æŽ¥çš„影响åQŒè€Œæ©¡èƒ¶äº¤è”度的降低,ä½?span>tan</span>δ增大åQŒå› æ­¤æ‘©æ“¦åŠ›å¢žå¤§åQŒæ‘©æ“¦ç³»æ•°å’Œ¼‚¨æŸä¹Ÿéšä¹‹å¢žå¤§ã€‚从物理化学的角度来看,交联­‘Šå¼±åQŒç£¨æŸçŽ‡­‘Šé«˜åQŒæ˜¯ç”׃ºŽè¾ƒä½Ž½E‹åº¦çš„交联易被机械应力破坏的¾~˜æ•…。研½I¶å‘玎ͼŒç”µå­æŸè¾ç…§å¯¼è‡´ä¹™ä¸™ä¸‰å…ƒæ©¡èƒ¶çš„交联度增加,使得摩擦降低ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> Š™¡èƒ¶è¡¨é¢è‡ªç”±èƒ½çš„高低军_®šäº†æ©¡èƒ¶ä¸Žå¯¹å¶é—´ç›¸äº’作用力的大ž®ï¼Œ˜q›è€Œå¯¹Š™¡èƒ¶çš„粘着摩擦产生影响。一般而言åQŒæ‘©æ“¦ç³»æ•°éšè¡¨é¢è‡ªç”±èƒ½çš„增加而增大ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> å¯ÒŽ©¡èƒ¶è¿›è¡Œå¡«å……改性时åQŒåœ¨æ”¹å˜Š™¡èƒ¶çš„物理力学性能的同æ—Óž¼Œä¹Ÿæ”¹å˜äº†Š™¡èƒ¶çš„摩擦学性能。研½I¶å•è½´å®šå‘聚酰胺¾U¤ç»´å¢žå¼ºçš„氯丁橡èƒ?span>(SFRR)</span>和芳¾U¶çŸ­¾U¤ç»´å¢žå¼ºçš„天然橡胶时åQŒå‘现材料的摩擦学行ä¸ÞZ¸Žæ»‘动方向密切相关åQŒæ²¿åž‚直于纤¾l´å–向方向摩擦时åQŒç£¨æŸçŽ‡æœ€ä½Žï¼Œæ²¿çº¤¾l´å–向摩擦时åQŒç£¨æŸæœ€å¤§ã€‚在抗æÑa性的丁腈Š™¡èƒ¶ã€æ°¯¼‚ºåŒ–聚乙烯橡胶、氟Š™¡èƒ¶ä¸­ï¼ŒåŠ å…¥æ¶¦æ»‘å‰?span>(</span>如有机硅沏V€?span>MoS<sub>2</sub></span>½{?span>)</span>后发çŽ?span>MoS<sub>2</sub></span>可在Š™¡èƒ¶è¡¨é¢å½¢æˆä¸€æ¶¦æ»‘层,能降低表面能和滞后效应,˜q›è€Œä‹É摩擦¾pÀL•°æ˜¾è‘—降低<sup><span>[21]</span></sup>ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> 利用自èín¼›Õd­è¾…助¼›Õd­é•€åQŒåœ¨Š™¡èƒ¶è¡¨é¢æ²‰ç§¯ä¸€å±‚铜、钛、钨、锆½{‰é‡‘属,能有效降低橡胶与对偶间的真实接触面积åQŒæ˜¾è‘—降低摩擦力。氯化也可降低橡胶的摩擦¾pÀL•°åŠå…¶å¯ÒŽ»‘动速度和温度的依赖性ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> Š™¡èƒ¶çš„摩擦与¾_˜å¼¹æ€§å‚æ•?span>tan</span>δ和弹性模量有直接关系åQŒå¼¹æ€§æ¨¡é‡éšæ¸©åº¦çš„升高而降低,<span>tan</span>δ则随温度的升高先上升后下é™?span>(</span>极值点温度低于<span>0</span>“ï<span>)<sup> </sup></span>。随温度的升高,Š™¡èƒ¶çš„弹性模量下降,¼‚¨æŸæ–‘纹间距增大。高温条件下åQŒç”±äºŽæ©¡èƒ¶è€åŒ–严重åQŒæ’•è£‚强度降低,使得¼‚¨æŸçŽ‡æ˜¾è‘—增加,òq¶ä¸”¼‚¨æŸçŽ‡å‘ˆå‘¨æœŸæ€§å¤§èŒƒå›´å˜åŒ–ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> 润滑剂的存在可阻止橡胶与对偶面的直接接触åQŒç²˜ç€æ‘©æ“¦æ˜Žæ˜¾é™ä½ŽåQŒæ©¡èƒ¶ç£¨¾_’磨损的斑纹间距减小åQŒç£¨æŸçŽ‡ä¹Ÿæ˜¾è‘—降低。但在选用润滑剂时åQŒå¿…™å»è€ƒè™‘它对Š™¡èƒ¶çš„溶胀作用åQŒä»¥åŠé«˜æ¸©æÑa润滑所å¯ÆD‡´çš„橡胶的化学降解或热降解åQŒå¦åˆ™å¯èƒ½ä¼šåŠ å‰§¼‚¨æŸã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> 在水<span>(</span>或水溶液<span>)</span>润滑条äšg下,随对偶的不同åQŒæ°´å¯ÒŽ©¡èƒ¶å’Œå¯¹å¶çš„摩擦磨损性能的媄响也不同。当对偶为惰性物è´?span>(</span>如玻ç’?span>)</span>æ—Óž¼Œæ°´å±‚可以起到非常好的润滑作用åQŒæ‘©æ“¦ç³»æ•°éšæ¶¦æ»‘膜膜厚的增加而降ä½?sup><span>[28]</span></sup>。当对偶较活泼时<span>(</span>如钢<span>)</span>Š™¡èƒ¶å‡ ä¹Žæ— ç£¨æŸï¼Œè€Œå¯¹å¶çš„¼‚¨æŸåˆ™æ¯”òq²æ‘©æ“¦æ—¶å¤§å¾—多ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> Š™¡èƒ¶å¯ÒŽœ‰æœºæº¶å‰‚及润滑剂的溶胀作用比较敏感。一般情况下åQŒæº¶èƒ€ä¼šç ´åæ©¡èƒ¶çš„交联体系åQŒå¼•èµäh©¡èƒ¶çš„¼‹¬åº¦ã€æ’•è£‚强度等力学性能降低åQŒå¯¼è‡´ç£¨æŸçš„增大ã€?span>Thavamani</span>½{‰ç”¨æ‰«æç”µå­æ˜‘Ö¾®é•?span>(SEM)</span>研究了硫化天然橡胶、丁苯橡胶、氢化丁腈橡胶在不同条äšg下的¼‚¨æŸæœºç†åQŒå‘现当法向载荷较小æ—Óž¼Œæ— å…¸åž‹çš„¼‚¨æŸæ–‘纹出现åQŒä½†Š™¡èƒ¶åœ¨ç”²è‹¯æˆ–二甲基甲酰胺中溶胀后,在其¼‚¨æŸè¡¨é¢å¯ä»¥è§‚察到明昄¡š„¼‚¨æŸæ–‘纹。这是因为橡胶溶胀后,其抗撕裂性能大大下降åQŒå¼¹æ€§æ¨¡é‡æ˜Žæ˜ùN™ä½Žï¼Œå› è€Œä¸Žæº¶èƒ€å‰ç›¸æ¯”,¼‚¨æŸæ–‘纹间距变大ã€?span></span></p><p class="MsoNormal" style="text-indent:24.0pt;"> 对于一些有‹zÀL³¼å®˜èƒ½å›¢çš„Š™¡èƒ¶<span>(</span>å¦?span>NBR</span>ã€?span>HNBR)</span>åQŒå¯åˆ©ç”¨å…¶åŒ–学活性较高的特点åQŒä‹É之与某种溶剂反应åQŒåœ¨Š™¡èƒ¶è¡¨é¢å½¢æˆä¸€å±‚化学反应膜来改善橡胶的摩擦学性能åQŒåˆ©ç”¨ç¢˜æº¶æ¶²çš„溶胀作用对丁腈橡胶进行了æ”ÒŽ€§ï¼Œæ”ÒŽ€§åŽçš?span>NBR</span>å’?span>HNBR</span>的摩擦系数明æ˜ùN™ä½Žã€‚碘与橡胶表面的氰基¾l“合形成一层薄而硬的改性层åQŒæ­¤æ”ÒŽ€§å±‚å…ähœ‰é™ä½Žæ‘©æ“¦çš„作用。然而,˜q‡åº¦æº¶èƒ€ä¼šä‹ÉŠ™¡èƒ¶å½¢æˆè¾ƒåŽšæ”ÒŽ€§å±‚åQŒå› å…¶ä¸Žå¼ÒŽ€§æœ¬ä½“çš„¾l“合性较差,反而会å¯ÆD‡´æ‘©æ“¦å¢žå¤§åQŒåŠ å‰§ç£¨æŸã€?span></span></p><p 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