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src="../../homes/view_left.asp?uid=70233"></SCRIPT> </td></tr> </table> </td> </tr> <tr><td height="10"></td></tr> </table> </td> <td width="10"></td> <td width="742" valign="top" align="center"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td class="solid-rw"> <table width="742" border="0" cellspacing="0" cellpadding="0"> <tr> <td height="32" class="center_bg"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr> <td width="56" align="center"><img src=/homes/images/yuanchuang.gif border=0></td> <td width="567" align="left"><span class="title">MDI体系注聚}酯的加工见Q一Q?/span>   <font color=#999999>(2019-9-9 14:26:28)</font></td> <td width="119" style="font-family:'宋体';"><img src="/space/images/zhuanlan.jpg" align="absmiddle"> <a href="/space/blog_post.asp" class="link3">发表博文</a></td> </tr> </table> </td> </tr> <tr><td height="" valign="top" align="center"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="left"> <tr> <td height="8"></td> </tr> <tr><td align="center" height="100" valign="top"> <table width="99%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr><td class=red_2 align=left><script src='/homes/Blog_tuijian.asp?Id=75409'></script></td></tr> <tr> <td align="left"> <table width="98%" border="0" cellspacing="0" cellpadding="0" align="center"> <tr> <td class="style_14_666666"> <div class="f401" id="f401"><p> <strong><span style="font-size:14px;color:#e53333;">本篇义堂108唐建功原创Q{载必M聚义堂取得联p,q标明文章出处!q者必IӞ</span></strong> </p><p> <strong><span style="font-size:16px;color:#003399;">一、材料的预处?/span></strong><br /><br /><strong>1、预聚体的脱泡处?/strong><br />预聚体里的气体主要有溶解的空气和预聚体微量吸潮后生成的二氧化组成,׃利定律可知,气体在液体里的溶解度随温度升高和压力降低而下降,因此我们可以采用升温同时抽真I的Ҏ脱Q徏议添加微量约0.03~0.05%的消泡剂?br /><br /><strong>2、多元醇l分的脱水处?/strong><br />?00~120度的条g下进行真I水处理?/p><p> <strong>3、固化剂的脱水处?/strong> </p><p> <strong>MDI体系大多采用14BG扩链Q有旉用HQEE、TMP{扩链?/strong> </p><p> 1.4BG极易吸潮Q而且低温很难脱净水分Q徏议在不低?20度有搅拌的条件下使用旋片式真I܇?0.1的极限真IZ脱水x气产生为止?a href="http://www.vflpel.live/jy_index.asp" target="_blank">HQEE、TMP</a>{扩铑։可以和多元醇一栯水?br /><br /><strong>4、其它助剂的处理Q?/strong><br />l 弱酸可以明显抑制反应的进行,但抗水解助剂会与酸反应?br />l 胺类或金属类催化剂可明显提高反应速度~短化旉Q但催化剂不可提前加到预聚体里,随着旉的g长会D预聚体凝胶?br />l 消剂对抑制气上升有明显效果,但有的耐磨剂会破坏消剂的功能?br /><br /><span style="font-size:16px;color:#003399;"><strong>二、温度设?/strong></span><br /><br /><strong>1?/strong><strong>MDI的反应活性高Q放热量大,所以不能采用太高的反应温度Q因此徏议预聚体升温到粘度适宜与固化剂Ҏ混合可以了?/strong><br /><br />一般与1.4BG固化Ӟ采用55~65度,但HQEE反应zL低而且易析出,因此与HQEE固化旉?10~120度?br /><br /><strong>2、硫化时1.4BG扩链的一般采?00~110度?/strong><br />采用HQEE扩链采用120度的化温度?br /><br /><strong>3、后化Q一般徏议后化温度100度,但硫化时间要保证16时以上Q厚制品24时以上?br /></strong><br /><br /><strong><span style="font-size:16px;color:#003399;">三、加工方?/span></strong><br /><br /><strong>1、开口浇?/strong><br /><br />如果采用手工搅拌Q必M证扩铑։d除水Q同时要注意防止<a href="http://www.vflpel.live" target="_blank">扩链?/a>其?.4BG的二ơ吸潮;必须留出_的脱泡时_因ؓMDI体系_度是逐步上升的,而且_度增加q速,气不易逸出Q真I泡徏议采用少量消泡剂Q徏议尽快进行高温硫化处理,其是做低硬度品;׃前期操作旉长,手工注的MDI体系聚}酯强度上升缓慢,q不如TDI/MOCA体系Q制品在脱模时容易损坏,一定要仔细操作?br /><br />采用注机则必须严格控制各组分比例,MDI体系对NCO与OH的؜合比例比TDI/MOCA体系要求的更H;采用注机浇注推荐用催化剂Q对ROSH6和耐水解没有特D要求的话T-9Q辛怺锡)卛_Q也可以选择?锌复合体pȝ催化剂?br /><br /><strong>2、模压成?/strong><br /><br /><span style="color:#000000;">MDI体系的模压与TDI/MOCA体系E有区别Q首先徏议用适量催化剂,催化剂合适的话脱模成型时间可以控制在20分钟以内。其ơ,MDI体系没有明显的凝胶点Q基本上需要在完全凝固甚至有一定硬度后再加压。最后,MDI体系需要更大的模压压力Q模h好能设计一个能够Ş成保压工艺的l构Q避免气体和多余的物料过早排出模腔?/span><br /><br /><span style="color:#337fe5;"><strong>以上内容׃人工作经验ȝ而来Q如有错漏之处请大家不吝指教Q也Ƣ迎各位同行一起交。不当之处,Ƣ迎大家指正批评!</strong></span><br />     <br /> <span style="color:#003399;"> </span><span style="color:#003399;"><strong>唐徏?/strong></span><br /><span style="color:#003399;"><strong>  9/9-2019</strong></span> </p><p> <span style="color:#003399;"><strong></strong></span> </p><p> <span style="color:#003399;"><span> <span style="color:#333333;"><em> </em></span><strong><span style="font-family:NSimSun;color:#4c33e5;"><em>本文作者唐建功</em></span></strong><span><strong><span style="font-family:NSimSun;color:#4c33e5;"><em>Q?/em></span></strong><span style="font-family:NSimSun;color:#4c33e5;"><em>1996q毕业于北京化工大学Q从事聚氨酯Ҏ体TPU、CPU生及后加工20多年Q现ȝ台博化学工业有限公司ȝ理。除自己生Ҏ体产品外,他还为弹性体制品企业提供技术服务,q多ơ担任PU聚义堂弹性体技术交年会及培训班的主讲老师。对大家提出的困惑,他L能用非常专业的知识讲解分析,Ҏ及化学反应的知识点如数家珍,深受大家的喜爱和好评?/em></span></span></span></span> </p></div> </td></tr></table> </td> </tr> <tr><td height="15" align="center"><SCRIPT src="/homes/din_1.asp?id=75409"></SCRIPT></td></tr> <tr><td height="5"></td></tr> <tr><td height="15" ><SCRIPT src="/homes/zan1.asp?id=75409"></SCRIPT></td></tr> <tr><td height="15"></td></tr> <tr> <td height="22" class="gray_999999"> <table width="100%" border="0" cellspacing="0" cellpadding="0"> <tr align="left"> <td width="1%"></td> <td width="42%">分类Q?a target='_blank' href=/publog/blog_all.asp?type=10>Ҏ体应用</a></td> <td width="21%"></td> <td width="17%">评论Q?font class="red_2"><script 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